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You Can Solve Most of the World’s problems With
a Good Adjuvant
OK, maybe that’s a stretch. But at the
very least, improve performance of your post emergence herbicides, which are getting more specific to their required adjuvants.
By Jason Hanson Certified Crop Advisor jlhanson@agriliance.com
With the upcoming post emergence weed control season upon us, it is time
to get the calculator out and start thinking ounces and pints per acre, gallons per 100, pressures and water volumes, anti-foam, tank cleaner and adjuvants.
Most of today’s post emerge products require some sort of adjuvant to enhance their performance or improve their consistency. But there is much confusion about adjuvants in
general, and almost all companies marketing them claim that theirs are better than the next guy’s stuff. In order to separate out the differences, we need to look at what an adjuvant is, and the types used with
certain products.
What is an adjuvant? An adjuvant is any additive used in conjunction with a pesticide to increase biological activity and/or to modify various physical properties of a spray solution.
That is a pretty broad explanation, but for effective weed control, herbicides must adequately contact the leaves, be absorbed in sufficient quantities,
move within that weed to its “site-of-action” and reach toxic levels at its “site-of-action” to effectively destroy that weed.
There are many physical variables that affect spray application, such as solubility, compatibility, foaming, droplet size, drift, surface tension,
volatilization, coverage, adherence and penetration. Adjuvants play a key role in helping to control those variables.
Adjuvants are classified into four categories:
- Activator adjuvants – These are the most common and help enhance pesticide performance. Products in this class are surfactants, crop oil
concentrates, methylated seed oils, basic blends, and fertilizer solutions. Almost everyone has used these products with most post emergent products.
- Spray modifier adjuvants – These affect the physical properties of spray solutions. Products in this class are stickers, deposition aids and drift products.
- Utility modifier adjuvants – This class helps minimize handling and application problems. Products in this group include compatability agents, buffering agents, anti-foam or de-foamers.
- Utility products – Basically these are used to help minimize application problems. These products are foam markers and tank cleaners.
Let’s look a bit closer, beginning with the two categories that generally cause the most confusion, activators and spray modifiers. There are certain
fits for each adjuvant, just as there is for each post applied chemical. So it is very important to know the difference and where they are to be used. Let’s
break down the activators into each product. I use Agriliance adjuvants as examples.
Non-Ionic Surfactants The most common product used is non-ionic surfactants (NIS). They are used in mostly water based chemistry like glyphosate but also have fits with
fungicides, insecticides and certain products like Everest, Aim, Distinct and Gramoxone Extra.
The purpose of a surfactant like Preference is to increase spray retention, allowing the pesticide to cover more area of the leaf and have a better chance of being absorbed.
Some weeds have very hairy leaf surfaces, and a surfactant aids in making sure that a spray mix droplet doesn’t get hung up on the leaf hairs and
evaporate. Be aware that when doing a tank mix with Puma, Bison, and Tilt, adding more/increasing the rate of surfactant might cause some crop
response, as there are solvents and formulations that get “hotter” when more is added to the tank, under certain weather conditions. Common use rates for non-ionic surfactants are 1-2 quarts/100 gallon.
Crop Oils These products act differently than non-ionic surfactants. Most crop oils, like Prime Oil or Superb HC have some surfactant or emulsifier in them, but
the largest component is made up of oils, either petroleum or vegetable. They are used with products like Rezult, Select, and Flexstar. These are oil
-based chemicals and do better with oil-based adjuvants, as the crop oil acts as a penetrator and basically melts that leaf cuticle away, allowing the chemical to enter.
Crop oil use rates are usually from 1 pint per acre up to 1 gallon per 100 gallons, depending on chemical being used.
The difference between crop oils and methylated seed oil (MSO) isn’t that large, until you get into specific herbicide types and environmental conditions
. Products like Raptor, Steadfast, Option, FirstRate, and Upbeet really like to have an MSO in the tank.
Notice that these chemicals are in the ALS class. That is because an MSO like Destiny has even greater activity than crop oils when it comes to cuticle
penetration and ultra violet degradation. When the weeds get taller than you would like them to be or the weather is drier and hotter, then the switch
from a crop oil to an MSO is warranted. Most of the time MSOs are recommended at 1% v/v basis (1 gal/100 gal of spray solution).
Basic pH blends Basic pH blends are a unique class and are used with mainly SU or IMI chemistries, like Silverado, Accent, Pursuit, Raptor, and Upbeet. They have
a surfactant portion and are non-oil. The difference with this class of adjuvant is that it raises the pH of the water solution, which increases the
solubility of the chemistry, thus making it more active. Newtone is our basic blend and is also used to help with precipitate issues with the micro rates in
sugarbeets. The performance of Newtone is very good when growing conditions are good. Newtone should be used in combination with Destiny in the micro rates. Common use rates with basic blends are 1 to 2 gallons
per 100 gallons.
Fertilizers Fertilizer solutions make up the last group in the activators. The most common fertilizers are 28% nitrogen and ammonium sulfate (AMS). These
are added in certain situations to enhance herbicide performance in combination with either a crop oil or an MSO. Rates of both 28% and AMS will depend on what product you are spraying.
Almost all glyphosate needs AMS, as it helps to condition water from things like calcium, magnesium, and iron, and also helps reduce antagonism that may occur on the leaf surface.
Products can vary. Some are promoted as water conditioning agents. Some contain straight rates of AMS, like Alliance or Class Act Next Generation,
while others like Arrow Four have reduced rates of AMS but are mainly built for convenient handling. Some contain additional surfactants along with the AMS. With all products, you have to weigh performance with
convenience, as weather conditions change and weed species are in need of different rates of AMS.
Spray modifiers The spray modifiers do just as their name implies; they change the spray solution or droplets. Some spreader-stickers are used with fungicide or
insecticide applications to retain product on hard to control leaves. I personally use Transfix with Bravo on my evergreens to help control needle
cast. It keeps the Bravo on the pine trees about a week longer and is indeed a sticker.
When it comes to drift control, there are two classes- the encapsulators (or droplet modifiers) and the thickeners. The thickeners will make the spray
solution get a latex look and makes the droplets a larger size, thus reducing the amount of fines that come out of your sprayer. These work very
effectively in visual reduction of drift, but can also reduce your spray pattern.
A thickener will take a 110-degree pattern and bring it down quite considerably, to like an 80 degree. Corral AMS Dry is an example of a
thickener. Thickeners come in liquid or dry forms and usually contain some amount of AMS in them. The early polymer products were referenced to as “snot in a jug” as they were sticky and not real pleasant to handle.
Encapsultors are invert emulsions that put chemical into certain size droplets for drift control. Even though it sounds like magic pixi dust, dealers that have
used products like Placement and Placement Propak have had great luck in managing off-target drift. These products manage the chemical, and do not affect the spray pattern.
The newest introduction to this group is Interlock, and has some encapsulation properties but mainly is a droplet modifier. Getting most of
your droplets into a 200-400 micron size helps with keeping product where it is needed. Interlock also has very good deposition qualities, making it have great fits with fungicides and insecticides.
Drift products fit into situations where liability and headaches are not wanted. They are a tool, but the main thing to consider when drift is a concern is the
product being used, wind speed and direction, pressure used, and common sense.
Use What’s Recommended And of course we can’t forget de-foamers and tank cleaners. I don’t really think of these products as adjuvants to improve/enhance herbicide
performance, per se. They have their place as products to use and have on hand to keep the tank full of water and not foam, and in the case of cleaners
, to clean all the lines and tank when switching herbicides, such as from glyphosate to small grain spraying.
Always read the label and match up your herbicide with the right adjuvant. Sometimes that additional cost of the additive is very small when it can
improve your performance, by 10% or more in some cases. All post emergence pesticides are getting more specific to their required adjuvants, so keep up to speed on the best fit for your spraying needs.
Hanson is a certified crop advisor near Devils Lake, N.D. Agriliance adjuvant web site: www.agriliance.com/1crop_protection/adjuvants
.asp .
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NDSU Tips on Choosing Adjuvants With Herbicides Several POST herbicides allow use of non-ionic surfactant, petroleum oil
additives, methylated seed oil additives, and nitrogen fertilizer. Questions about adjuvant selection are common. MSO type additives have often given
greater weed control than petroleum oil additives and non-ionic surfactants (NIS) but cost up to 2 to 3 times more. The added cost of MSOs and
increased risk of crop injury when used at high temperatures have deterred people from using this class of adjuvants.
Some herbicide labels restrict use of oil adjuvants and recommend only the use of NIS alone or combined with nitrogen based fertilizer solutions.
Follow label directions for adjuvant selection. Where labels allow use of oil additives, a petroleum oil based adjuvant referred to as crop oil concentrates (COC) or methylated seed oil (MSO) adjuvants may be used.
The term crop oil concentrate is misleading and incorrect. The base substance in COC is petroleum oil based ingredients, not crop oil based.
NDSU research has shown wide difference in adjuvant enhancement of herbicides. However, in many studies, no or small differences occur
depending on environmental conditions at application, growing conditions of weeds, rate of herbicide used, and size of weeds. For example, under warm
, humid conditions with actively growing weeds, NIS + nitrogen fertilizer may enhance weed control the same as oil additives. The following are conditions where MSO type additives may give greater weed control than
other adjuvant types:
Conditions That Favor Use of MSO Type Adjuvants
- Low humidity, hot weather, lack of rain, and drought stressed weeds or weeds not actively growing due to some condition causing stress.
- Weeds larger than recommended on the label.
- Herbicides used at reduced rates.
- Target weed or weeds are somewhat tolerant to the herbicide. For example, control of wild buckwheat, biennial wormwood, common
lambsquarters or ragweed with Pursuit or Raptor, or control of yellow foxtail with Accent.
- When university data supports use. Only some herbicides give greater weed control when used with MSO type adjuvants. For example:
Accent, Pursuit, Raptor, and UpBeet have shown greater weed control when used with an MSO type adjuvant compared to a NIS. Also, glyphosate should never be used with an oil adjuvant because
glyphosate is very water soluble (water + oil don't mix) and the added cost of an MSO is not necessary.
– NDSU Extension Service
NDSU list of adjuvant products and approximate prices: www.ag.ndsu.nodak.edu/weeds/w253/w253-5d.htm#Adjuvant
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